1ST C-4 BRIDGED MIXED-VALENCE IRON(II)-IRON(III) COMPLEX DELOCALIZED ON THE INFRARED TIMESCALE

被引：0

作者：

LENARVOR, N

LAPINTE, C

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 04期

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中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first 35-electron acetylide bridged diiron complex [{Fe(eta5-C5Me5)(dppe)}2(mu-C4)]PF6, 3PF6, [dppe = ethylenebis(diphenylphosphine)] and the 36- and 34-electron bis-iron(II) and bis-iron(III) homologous derivatives are synthesized and it is established that the Fe(II)-Fe(III) complex is the first non-trapped mixed-valence compound with two half-sandwich monomeric units joined by a C4 bridge.

引用

页码：357 / 359

页数：3

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