HYDRODENITROGENATION OF SIMPLE AROMATIC-AMINES ON MOLYBDENA CATALYSTS - NATURE OF ACTIVE-SITES

被引：0

作者：

SHANTHI, K ^{[1
]}

PILLAI, CN ^{[1
]}

KURIACOSE, JC ^{[1
]}

机构：

[1] INDIAN INST TECHNOL, DEPT CHEM, MADRAS 600036, TAMIL NADU, INDIA

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1991年 / 30卷 / 07期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pretreatment of Ni-promoted MoO3/Al2O3 with H2S/H2 leads to an increase in the number of coordinatively unsaturated molybdenum sites and also an increase in hydrodenitrogenation activity (HDN). Presence of H2S in the feed increases the activity for hydrogenolysis of C(sp3) - N bond and decreases the activity for hydrogenolysis of C(sp2) - N bond. The activity for hydrogenolysis of C(sp3) - N bond is attributed to protonic sites and that for the hydrogenolysis of C(sp2) - N bond to anion vacancies associated with molybdenum.

引用

页码：584 / 587

页数：4

共 50 条

[1] HYDRODENITROGENATION OF SIMPLE AROMATIC-AMINES ON MOLYBDENA CATALYSTS
SHANTHI, K
PILLAI, CN
KURIACOSE, JC
[J]. APPLIED CATALYSIS, 1989, 46 (02): : 241 - 249
[2] THE MECHANISMS AND THE SITES OF THE HYDRODENITROGENATION REACTION FOR SEVERAL AROMATIC-AMINES .1.
LEDOUX, MJ
[J]. APPLIED CATALYSIS, 1984, 9 (01): : 31 - 40
[3] ACTIVE-SITES OF A REDUCED MOLYBDENA-ALUMINA CATALYST - A TRANSIENT STUDY OF HYDRODENITROGENATION OF CARBAZOLE AND ACRIDINE
NAGAI, M
MASUNAGA, T
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1989, 62 (03) : 972 - 974
[4] IDENTIFICATION OF CATALYTICALLY ACTIVE-SITES ON REDUCED MOLYBDENA-ALUMINA CATALYSTS
MILLMAN, WS
HALL, WK
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1979, 83 (03): : 427 - 428
[5] ON THE NATURE OF CATALYTIC ACTIVE-SITES ON MOLYBDENUM CATALYSTS
HOLL, Y
GARIN, F
MAIRE, G
[J]. JOURNAL OF CATALYSIS, 1988, 113 (02) : 569 - 571
[6] THE NATURE OF HDSHDN ACTIVE-SITES IN SULFIDE CATALYSTS
BRENNER, JR
THOMPSON, LT
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 206 : 114 - PETR
[7] STUDY OF THE NATURE AND STABILITY OF ACTIVE-SITES IN VANADIUM PHOSPHATE CATALYSTS
HARROUCH, N
BATIS
BATIS, H
[J]. BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 1993, 130 (06): : 807 - 816
[8] NATURE OF THE ACTIVE-SITES OF PALLADIUM CATALYSTS OF THE OXIDATIVE ACETOXYLATION OF TOLUENE
STARCHEVSKII, MK
VARGAFTIK, MN
MOISEEV, II
[J]. KINETICS AND CATALYSIS, 1979, 20 (05) : 955 - 961
[9] THE NATURE OF THE ACTIVE-SITES IN THE REACTIONS OF CUMENE ON HY AND LAY CATALYSTS
CORMA, A
WOJCIECHOWSKI, BW
[J]. CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1980, 58 (05): : 620 - 625
[10] SIMPLE AND CONVENIENT DEAMINATION OF AROMATIC-AMINES
CADOGAN, JIG
MOLINA, GA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1973, (06): : 541 - 542

← 1 2 3 4 5 →