N-P-TOLYLVANILLALDIMINE, C15H15NO2

被引：11
|
作者：
KAITNER, B
PAVLOVIC, G
机构：
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷
关键词：
D O I：
10.1107/S0108270195002824
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, 2-methoxy-4-(p-tolyliminomethyl)-phenol, contains two phenyl rings bridged by a C=N imino moiety, the planes of which are inclined at an angle of 40.26 (9)degrees, showing significant deviation of the molecule from planarity. The characteristic of aromatic Schiff bases with N-aryl substituents is that the terminal phenyl rings are twisted relative to the plane in which the C=N double bond lies. The hydroxy group is involved simultaneously in intramolecular and intermolecular three-centre hydrogen bonding with two acceptor atoms. Adjacent molecules are linked via an intermolecular O-H ... N hydrogen bond [O1 ... N1 2.839 (3) Angstrom, O1-H1 ... N1 154.9 degrees] forming infinite chains along the y axis.
引用
收藏
页码：1875 / 1878
页数：4
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