SELECTIVE OXIDATION OF POLY(4-METHYLSTYRENE)

被引：11

作者：

SHAVER, RT ^{[1
]}

VLAOVIC, D ^{[1
]}

REVIAKINE, I ^{[1
]}

WITTAKER, R ^{[1
]}

FERRARI, LP ^{[1
]}

STOVER, HDH ^{[1
]}

机构：

[1] MCMASTER UNIV,DEPT CHEM,HAMILTON,ON L8S 4M1,CANADA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1995年 / 33卷 / 06期

关键词：

POLY(4-METHYLSTYRENE); CATALYTIC OXIDATION; FUNCTIONAL POLYMERS;

D O I：

10.1002/pola.1995.080330609

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A range of new functional copolymers bearing aldehyde and carboxylic acid groups have been prepared by functionalization of poly(4-methylstyrene). These polymers have molecular weights from 2,000 to 16,500 and contain up to 20% aldehyde and up to 90% carboxylic acid groups. The reaction proceeds by selective catalytic oxidations with molecular oxygen or air in acetic acid/organic cosolvent mixtures in presence of cobalt acetate and sodium bromide or hydrogen bromide. The effects of reaction temperature, catalyst, co-solvents and oxygen partial pressure on the reaction are described. (C) 1995 John Wiley and Sons, Inc.

引用

页码：957 / 965

页数：9

共 50 条

[1] Selective functionalization of poly(4-methylstyrene)
Sheng, Q
Stover, HDH
[J]. MACROMOLECULES, 1997, 30 (21) : 6451 - 6457
[2] COBALT-CATALYZED OXIDATION OF POLY(4-METHYLSTYRENE)
FERRARI, LP
STOVER, HDH
[J]. MACROMOLECULES, 1991, 24 (23) : 6340 - 6342
[3] EFFECTIVE DIPOLE MOMENT OF POLY(4-METHYLSTYRENE)
CORRADO, LC
[J]. JOURNAL OF CHEMICAL PHYSICS, 1969, 50 (05): : 2260 - &
[4] Selective modification of 4-methylstyrene polymers.
Sheng, Q
Stover, HDH
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 213 : 52 - PMSE
[5] Effect of molecular weight on the miscibility of polystyrene and poly(4-methylstyrene).
Emor, W
Chang, LL
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U277 - U277
[6] PHASE-TRANSFER-CATALYZED CHLORINATION OF POLY(4-METHYLSTYRENE) BY HYPOCHLORITE
JONES, RG
MATSUBAYASHI, Y
[J]. POLYMER, 1990, 31 (08) : 1519 - 1525
[7] Prediction and experimental verification on blend phase diagrams of two structurally isomeric polymers:: Poly(4-methylstyrene) and poly(α-methylstyrene)
Chang, LL
Woo, EM
[J]. MACROMOLECULES, 2000, 33 (18) : 6892 - 6895
[8] The thermo-oxidative degradation of poly(4-methylstyrene) and its relationship to flammability
McCreath, S.
Lewicki, J. P.
Liggat, J. J.
Lithgow, C.
McCulloch, L.
Miller, K.
Witkowski, A.
[J]. POLYMER DEGRADATION AND STABILITY, 2015, 113 : 144 - 153
[9] Morphology, phase diagrams, and UCST behavior in blends of polystyrene with poly(4-methylstyrene)
Chang, LL
Woo, EM
[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 2001, 202 (05) : 636 - 644
[10] A Boron Subphthalocyanine Polymer: Poly(4-methylstyrene)-co-poly(phenoxy boron subphthalocyanine)
Dang, Jeremy D.
Virdo, Jessica D.
Lessard, Benoit H.
Bultz, Elijah
Paton, Andrew S.
Bender, Timothy P.
[J]. MACROMOLECULES, 2012, 45 (19) : 7791 - 7798

← 1 2 3 4 5 →