ENANTIOSELECTIVE CATALYSIS .4. SYNTHESIS OF N-SUBSTITUTED (R,R)-3,4-BIS(DIPHENYLPHOSPHINO)PYRROLIDINES - THE USE OF THEIR RHODIUM COMPLEXES FOR THE ASYMMETRIC HYDROGENATION OF ALPHA-(ACYLAMINO)ACRYLIC ACID-DERIVATIVES

被引：168

作者：

NAGEL, U ^{[1
]}

KINZEL, E ^{[1
]}

ANDRADE, J ^{[1
]}

PRESCHER, G ^{[1
]}

机构：

[1] DEGUSSA AG,FORSCH CHEM ORGAN,D-6450 HANAU 11,FED REP GER

来源：

CHEMISCHE BERICHTE-RECUEIL | 1986年 / 119卷 / 11期

关键词：

D O I：

10.1002/cber.19861191112

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：3326 / 3343

页数：18

共 9 条

[1] SYNTHESIS AND APPLICATION OF (3R,4R)-3,4-BIS(DIPHENYLPHOSPHINO)TETRAHYDROFURAN AS LIGAND FOR ASYMMETRIC HYDROGENATION OF ACRYLIC ACIDS
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[2] SYNTHESIS OF 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL (BINAP), AN ATROPISOMERIC CHIRAL BIS(TRIARYL)PHOSPHINE, AND ITS USE IN THE RHODIUM(I)-CATALYZED ASYMMETRIC HYDROGENATION OF ALPHA-(ACYLAMINO)ACRYLIC ACIDS
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[3] ENANTIOSELECTIVE CATALYSIS, .5. NEW LIGANDS WITH 4 STEREOGENIC CENTERS - SYNTHESIS AND SEPARATION OF THE 3 DIASTEREOMERIC [P(R,S),3R,4R,P'(R,S)]-3,4-BIS(METHYLPHENYLPHOSPHINO)-PYRROLIDINES
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[4] ASYMMETRIC REACTIONS CATALYZED BY CHIRAL METAL-COMPLEXES .38. EFFICIENT ASYMMETRIC HYDROGENATION OF (Z)-2-ACETAMIDOCINNAMIC ACID CATALYZED BY THE RHODIUM COMPLEX OF MODIFIED N-BENZYL-(3R,4R)-3,4-BIS(DIPHENYLPHOSPHINO)PYRROLIDINE (DEGPHOS)
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[5] ENANTIOSELECTIVE CATALYSIS .7. COMPLEXES OF (P(R,S),3R,4R,P'(R,S))-3,4-BIS(PHENYLPHOSPHINO)PYRROLIDINES - SYNTHESIS OF OPTICALLY PURE 1,2-BISPHOSPHANE LIGANDS WITH 4 STEREOCENTERS WHICH CONTAIN ADDITIONAL FUNCTIONAL-GROUPS
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[6] PHOSPHINITES OF CARBOHYDRATES AS CHIRAL LIGANDS FOR ASYMMETRIC-SYNTHESIS CATALYZED BY COMPLEXES .4. INFLUENCE OF THE SOLVENT AND THE STRUCTURE OF CATIONIC 4,6-0-BENZYLIDENE-2,3-0-BIS(DIPHENYLPHOSPHINO)-D-HEXOPYRANOSIDE-RHODIUM(I) CHELATES ON ENANTIOSELECTIVITY IN HYDROGENATION OF DEHYDROAMINO ACID-DERIVATIVES
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[7] PHOSPHINITES OF CARBOHYDRATES AS CHIRAL LIGANDS FOR ASYMMETRIC-SYNTHESIS CATALYZED BY COMPLEXES .2. SUPERIORITY OF PHENYL 4,6-O-(R)-BENZYLIDENE-2,3-O-BIS(DIPHENYLPHOSPHINO)-BETA-D-GLUCOPYRANOSIDE FOR RHODIUM(I)-CATALYZED HYDROGENATION OF AMINO-ACID PRECURSORS
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[J]. JOURNAL OF MOLECULAR CATALYSIS, 1986, 37 (2-3): : 213 - 225
[8] PHOSPHINITES OF CARBOHYDRATES AS CHIRAL LIGANDS FOR ASYMMETRIC-SYNTHESIS CATALYZED BY COMPLEXES .3. IMMOBILIZATION OF CATIONIC RHODIUM(I) CHELATES OF PHENYL 4,6-O-(R)-BENZYLIDENE-2,3-O-BIS(DIPHENYLPHOSPHINO)-BETA-D-GLUCOPYRANOSIDE ON CATION EXCHANGERS FOR HYDROGENATION OF DEHYDROAMINO ACIDS
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[9] ENANTIOSELECTIVE 2-PHASE HYDROGENATION OF ALPHA-AMINO-ACID PRECURSORS WITH WATER-SOLUBLE RHODIUM COMPLEXES OF THE CATIONIC LIGAND (S,S)-2,4-BIS[BIS-(P-N,N,N-TRIMETHYLAMMONIUMPHENYL)PHOSPHINO]PENTANE, [CH3CH(P(P-C6H4NME3)2CH2CH(P(P-C6H4NME3)2CH3]4+
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[J]. CATALYSIS LETTERS, 1990, 5 (02) : 183 - 188

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