A STUDY OF ETA-3-ALLYL(ETA-5-CYCLOPENTADIENYL)-DICARBONYLMANGANESE SALTS

被引：4
|
作者：
KNOX, GR
PAUSON, PL
ROONEY, J
机构：
[1] Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, G1 1XL Scotland, Cathedral Street
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 420卷 / 03期
关键词：
D O I：
10.1016/0022-328X(91)86466-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New substituted eta-3-allyl(eta-5-cyclopentadienyl)dicarbonylmanganese cations have been prepared as their tetrafluoroborates. They readily add a wide range of nucleophiles yielding eta-2-alkene(eta-5-cyclopentadienyl)dicarbonylmanganese complexes. Of the latter, in general only those involving terminal alkenes are sufficiently stable to permit ready isolation; otherwise metal-free alkenes are obtained. Regioselectivity in these additions depends on the nucleophile.
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页码：379 / 389
页数：11
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