Structure of Core-Shell Ni/Au Nanoparticles Synthesized in Two-Stage Process From Aqueous Salt Solutions

被引:0
|
作者
Zaharov, Yu. A. [1 ,2 ]
Dodonov, V. G. [1 ]
Pugachev, V. M. [1 ]
Russakov, D. M. [1 ]
Ivanova, N. V. [1 ]
Kolmykov, R. P. [1 ]
Yeremenko, N. K. [2 ]
Obraztsova, I. I. [2 ]
机构
[1] Kemerovo State Univ, Inst Coal Chem & Mat Sci SB RAS, Krasnaya st 6, Kemerovo 650043, Russia
[2] Inst Coal Chem & Mat Sci SB RAS, Kemerovo 650000, Russia
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O6 [化学];
学科分类号
0703 ;
摘要
Core-shell Ni/Au nanoparticles are synthesized in a two-stage process in aqueous solutions. The core-shell structure of the synthesized particles is proven by using results of HRTEM, TEM, SAXS and CVA methods. The thickness of the core is estimated at 1 nm and it is formed from 1-2 layers of mutually oriented gold crystallites. The CVA results show that the Au-shells are nanoporous, and that a layer of nickel oxidation products is formed. These results were obtained by using Vis spectrophotometer, TEM, HRTEM, SAXS, CVA and elemental analysis.
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页码:267 / 274
页数:8
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