Preparation and catalytic activity of polymer-bound 1,10-phenanthroline and its complexes

被引：16
|
作者：
Wang, RM [1 ]
Li, SB
Wang, YP
Chang, Y
He, YF
Lei, ZQ
Feng, HX
机构：
[1] NW Normal Univ, Dept Chem, Lanzhou 730070, Peoples R China
[2] Acad Sinica, Lanzhou Inst Chem Phys, OSSO Key State Lab, Lanzhou 730000, Peoples R China
来源：
REACTIVE & FUNCTIONAL POLYMERS | 1999年 / 42卷 / 01期
关键词：
polymer-bound complex; 1,10-phenanthroline; ferric complex; oxidation;
D O I：
10.1016/S1381-5148(98)00061-3
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Polymer-bound 1,10-phenanthroline (PS-phen) has been prepared by reaction of chloromethylated polystyrene with 5-amino-1,10-phenanthroline. The polymer-bound ligand and its complexes (PS-phenFephen) were characterized by IR spectroscopy and XPS. The polymer bound ferric complexes, which are N,N,N,N-type complexes, show high catalytic selectivity in the oxidation of substituted benzene. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：87 / 92
页数：6
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