FORMATION OF POLY(2,5-DIBUTOXY-1,4-PHENYLENEVINYLENE) AT ROOM-TEMPERATURE IN CHCL3 CATALYZED BY CHCL3 PHOTOPRODUCTS

被引：17
|
作者：
DELMOTTE, A
BIESEMANS, M
RAHIER, H
GIELEN, M
MEIJER, EW
机构：
[1] FREE UNIV BRUSSELS,FYSC,B-1050 BRUSSELS,BELGIUM
[2] EINDHOVEN UNIV TECHNOL,DEPT ORGAN CHEM,5600 MB EINDHOVEN,NETHERLANDS
来源：
SYNTHETIC METALS | 1993年 / 58卷 / 03期
关键词：
D O I：
10.1016/0379-6779(93)91141-N
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A convenient, mild preparation of poly(2,5-dibutoxy-1,4-phenylenevinylene) (DBOPPV) using a modified precursor route is reported. The conversion of the. methoxy pendent precursor polymer into its conjugated form is performed in chloroform by the elimination of methanol at room temperature, yielding DBOPPV as a red solution. The elimination is thought to be catalysed by the acid photoproducts of chloroform.
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页码：325 / 334
页数：10
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