THEORY OF SPECTROELECTROCHEMISTRY UNDER GALVANOSTATIC CONDITIONS .2. IRREVERSIBLE AND QUASI-REVERSIBLE SIMPLE CHARGE-TRANSFER REACTIONS

被引:4
|
作者
UZIEL, Z
机构
[1] Silesian Polytechnical Univ, Gliwice, Pol, Silesian Polytechnical Univ, Gliwice, Pol
关键词
ELECTROCHEMISTRY; -; Theory; ELECTRODES;
D O I
10.1016/0013-4686(87)85020-X
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
This paper deals with a new mathematical formulation of methods for spectrochemical examination of irreversible O plus ne** minus (k)**f**,**h yields R and quasi-reversible O plus ne** minus (k)**f**,**h reversible reaction //k //b//,//h R simple charge transfer reactions on planar electrodes under conditions of semi-infinite linear diffusion making use of electrolysis under galvanostatic conditions. The principal equations relating to electrode potential and transition absorbances of the spectrally monitored species of O or R are derived. A possibility of determining the parameters of electrode process from measurements by transmission or reflection spectroscopy methods is presented.
引用
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页码:497 / 501
页数:5
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