GAMMA-RADIOLYSIS STUDY OF CONCENTRATED NITRIC-ACID SOLUTIONS

被引：42
|
作者：
JIANG, PY [1 ]
NAGAISHI, R [1 ]
YOTSUYANAGI, T [1 ]
KATSUMURA, Y [1 ]
ISHIGURE, K [1 ]
机构：
[1] UNIV TOKYO,FAC ENGN,DEPT QUANTUM ENGN & SYST SCI,BUNKYO KU,TOKYO 113,JAPAN
来源：
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1994年 / 90卷 / 01期
关键词：
D O I：
10.1039/ft9949000093
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The formation of nitrous acid has been studied in the Co-60-gamma radiolysis of concentrated nitric acid solutions. The yields of nitrous acid are proportional to the electron fraction of nitric acid, on the basis of which, an additional reaction path, NO3- (W)-->O(P-3)+ NO2- with a primary yield of 0.16 mu mol J(-1), has been verified for the direct action of radiation on nitric acid.
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页码：93 / 95
页数：3
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