SYNTHESIS AND REACTIVITY OF SOME N,N-BIS(3-NITROBENZYLIDENE)ETHYLENE-DIAMINE DIPHENYLTIN SALTS

被引：3
|
作者：
SHUKLA, PR [1 ]
SHARMA, MC [1 ]
NARAIN, G [1 ]
机构：
[1] SAGAR UNIV,DEPT CHEM,SAGAR 470003,INDIA
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1990年 / 20卷 / 05期
关键词：
D O I：
10.1080/00945719008048158
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of seven new complexes of organotin(IV) of the general formula [Ph2SnLjX2 where L = N,N-bis(3-nitrobenzylidene) ethylenediamine and X = Cl, ClO-4, NO-3, BF-4 have been prepared and their reactivity, using a variety of reagents and resulting in ten new derivatives, has been studied. The Sn-C bond remains stable and intact in many interesting interconversions of these derivatives and the functional groups on the 3-position of benzene ring were found to be intramolecularly coordinated to the tin atom giving octahedral geometry to the new complexes. © 1990, Taylor & Francis Group, LLC. All rights reserved.
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页码：583 / 598
页数：16
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