PHOSPHINE-BORANES IN SYNTHESIS - BORANE AS AN EFFICIENT PROTECTING GROUP IN THE PREPARATION OF FUNCTIONALIZED PHOSPHINES

被引:63
|
作者
PELLON, P
机构
[1] Laboratoire de Synthe`se Organique, Associe ́au CNRS. Universite ́de Rennes I, 35 042 Rennes, Avenue du Ge ne ral Leclerc
关键词
D O I
10.1016/S0040-4039(00)60107-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Phosphines bearing an aldehyde, a ketone or a carboxyl on the side chain can be prepared by oxidation of the hydroxyalkylphosphine-borane complexes followed by decomplexation using dietkylamine.
引用
收藏
页码:4451 / 4452
页数:2
相关论文
共 50 条
  • [1] SYNTHESIS AND REACTIONS OF PHOSPHINE-BORANES
    IMAMOTO, T
    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1993, 51 (03) : 223 - 231
  • [2] The Hydroxyalkyl Moiety As a Protecting Group for the Stereospecific Alkylation of Masked Secondary Phosphine-Boranes
    Lemouzy, Sebastien
    Jean, Marion
    Giordano, Laurent
    Herault, Damien
    Buono, Gerard
    ORGANIC LETTERS, 2016, 18 (01) : 140 - 143
  • [3] Synthesis and structure of cyclic phosphine-boranes
    Schmidbaur, H
    Sigl, M
    Schier, A
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 529 (1-2) : 323 - 327
  • [4] Preparation of NHC Borane Complexes by Lewis Base Exchange with Amine-and Phosphine-Boranes
    Biahmi, Malika Makhlouf
    Monot, Juhen
    Desage-El Murr, Marine
    Curian, Dennis P.
    Fensterbank, Louis
    Lacote, Emmanuel
    Malacna, Max
    JOURNAL OF ORGANIC CHEMISTRY, 2010, 75 (20): : 6983 - 6985
  • [5] A NEW SYNTHESIS OF AMINE- AND PHOSPHINE-BORANES
    NAINAN, KC
    RYSCHKEW.GE
    INORGANIC CHEMISTRY, 1969, 8 (12) : 2671 - &
  • [6] Nucleophilic displacement of ammonia from ammonia borane for the preparation of alkylamine-, pyridine- and phosphine-boranes
    Ramachandran, P. Veeraraghavan
    Kulkarni, Ameya S.
    RSC ADVANCES, 2014, 4 (50): : 26207 - 26210
  • [7] One-pot transformation of cyclic phosphine oxides to phosphine-boranes by dimethyl sulfide-borane
    Keglevich, György
    Fekete, Melinda
    Chuluunbaatar, Tungalag
    Dobó, András
    Harmat, Veronika
    Toke, László
    Journal of the Chemical Society, Perkin Transactions 1, 2000, (24): : 4451 - 4455
  • [8] SYNTHESIS AND REACTIONS OF OPTICALLY-ACTIVE PHOSPHINE-BORANES
    IMAMOTO, T
    OSHIKI, T
    ONOZAWA, T
    MATSUO, M
    HIKOSAKA, T
    YANAGAWA, M
    HETEROATOM CHEMISTRY, 1992, 3 (5-6) : 563 - 575
  • [9] One-pot transformation of cyclic phosphine oxides to phosphine-boranes by dimethyl sulfide-borane
    Keglevich, G
    Fekete, M
    Chuluunbaatar, T
    Dobó, A
    Harmat, V
    Toke, L
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2000, (24): : 4451 - 4455
  • [10] One-pot transformation of cyclic phosphine oxides to phosphine-boranes by dimethyl sulfide-borane.
    Keglevich, G
    Fekete, M
    Chuluunbaatar, T
    Dobó, A
    Harmat, V
    Toke, L
    MAGYAR KEMIAI FOLYOIRAT, 2001, 107 (12): : 538 - 543