STATISTICAL-MECHANICS OF IONOMERIC COLLOIDS .2. IONOMER CONFORMATIONAL EQUILIBRIA

被引：12
|
作者：
RONIS, D
机构：
[1] Department of Chemistry, McGill University, Montreal, Quebec, H3A 2K6
来源：
MACROMOLECULES | 1993年 / 26卷 / 08期
关键词：
D O I：
10.1021/ma00060a034
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Conformational equilibria in the charged region of spherical ionomeric colloids are studied using a self-consistent mean-field Monte Carlo method. It is shown that the ionomers do not adopt a single type of conformation but instead exhibit both rodlike and swollen coil like regions. The extent of these regions can be controlled by varying the screening length, curvature of the colloid core, and aggregation number.
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页码：2016 / 2024
页数：9
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