NEW, NONSYMMETRICAL 2/2 PHTHALOCYANINES, 1,2,3,4,15,16,17,18-OCTAPHENYL-9,23(24)-DINITROPHTHALO-11,29(30)-DI-TERT-BUTYLDINAPHTHALOCYANIN AND 1,2,3,4,19,20,21,22-OCTAPHENYLDIPHTHALO-11,29(30)-DI-TERT-BUTYLDINAPHTHALOCYANINE COPPER-COMPLEXES

被引：0

作者：

NEMYKIN, VN ^{[1
]}

SUBBOTIN, NB ^{[1
]}

KOSTROMINA, NA ^{[1
]}

VOLKOV, SV ^{[1
]}

机构：

[1] NATL ACAD SCI UKRAINE,INST GEN & INORGAN CHEM,KIEV 252680,UKRAINE

来源：

MENDELEEV COMMUNICATIONS | 1995年 / 02期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction between tetraphenylphthalonitrile and 4-phthalonitrile or 6-terf-butylnaphthalonitrile in the presence of copper(1) chloride gives a non-statistical mixture of non-symmetrical phthalocyanines from which 2:2 complexes are separated; in the reaction between substituted phthalo- and naphthalonitriles the 2:2 complex was a major product. The splitting of the Q-band in the electronic spectra depends on the differences in the electronic structure of the fragments of the non-symmetrical molecule.

引用

页码：71 / 72

页数：2

共 10 条

[1] New, Non-symmetrical 2:2 Phthalocyanines. 1,2,3,4,15,16,17,18-Octaphenyl-9,23(24)-dinitrophtha lo- and 1,2,3,4,19,20,21,22-Octaphenyldiphthalo-11,29(30)-di -tert$ MIN@butyldinaphthalocyanine Copper Complexes
Nemykin, V. N.
Subbotin, N. B.
Kostromina, N. A.
Volkov, S. V.
Mendeleev Communications, 1995, (02)
[2] Crystal structure of μ-13,27-di-tert-butyl-3,6,9,17,20,23-hexaazatricyclo-[23,3,1,111,15]triaconta-1(28),11,13,15 (30),25,26-hexaene-29,30-diolato[κ5N3,N6,N9,O29,O30:κ5N17,N20,N23,O29,O30]bis(thiocyanato-κN)-cobalt(II) - methanol (1:2), Co2(C32H52N6O2)(NCS)2•2CH3OH
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[3] Crystal structure of [μ-13,27-di-tert-butyl-3,6,9,17,20,23-hexaazatricyclo[23,3,1,11,15]triaconta-1(28),11,13,15 (30),25,26-hexaene-29,30-diolato[κ5N3,N6,N9,O29,O29,O30:κ5N17,N20,N23,O29,O30]bis(thiocyanato-κN)-nickel(II) - methanol (1:0.5), Ni2(C32H52N6O2)(NCS)2 • 0.5CH3OH
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[5] Crystal structure of tetraethyl 27,30-dioxo-7,12,20,25-tetra-tert-butyl-3,16-dioxa-9,22,28,31-tetrathiaheptacyclo [21.3.1.1(1,5).1(4,8).1(10,14).1(14,18).1(17,21)]-dotriaconta-4,6,8(29),10,12,17,19,- 21 (32),23,25-decaene-2,2,15,15-tetra-carboxylate
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[6] CRYSTAL-STRUCTURES OF COMPLEXES BETWEEN ALKALI-METAL SALTS AND CYCLIC POLYETHERS .10. COMPLEX FORMED BETWEEN 6,7,9,10,12,13,15,16,-23,24,26,27,29,30,32,33-HEXADECAHYDRODIBENZO[B,Q][1,4,7,10,13,16,19,22,-25,28]DECAOXACYCLOTRIACONTIN (DIBENZO-30-CROWN-10) AND 2 MOLECULES OF SODIUM ISOTHIOCYANATE
OWEN, JD
TRUTER, MR
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[7] PREPARATION AND SPECTROSCOPIC PROPERTIES OF COBALT(III), NICKEL(II), COPPER(II) AND ZINC(II) COMPLEXES WITH A NOVEL SATURATED MACROCYCLIC LIGAND - 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22-DOCOSAHYDRODIBENZO-[B,I][1,4,8,11] TETRAAZACYCLOTETRADECINE
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[8] [μ-10,21-di-tert-butyl-4(S),5(S),15(S),16(S)-tetra-phenyl-3,6,14,17-tetraazatricyclo[17.3.1.18,12]-tetracosa-1 (23),2,6,8,10,12 (24),13,17,19,21-decaene-23,24-diolatol(μ-ethylene glycol)-dinickel(II) diperchlorate dihydrate
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[9] Crystal structure of (1α,2β,3α,4β,5α,12α,13β,14α,15β,16α,17β,18α,25α,26β)-N-(2-methoxyethyl)-5,12,18,25-tetraphenyl-27,28,29,30-tetraoxadeca-cyclo-[14.10.1.13,14.15,12.118,25.02,15.04,13.06,11.017,26.019,24]triaconta-6,8,10,19,21,23-hexaen-2,15-carboximide -: chloroform (1/2), C55H43NO7 • 2CHCl3
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[10] μ-Acetato-κ2O:O′-[7,23-dibenzyl-15,31-dichloro-3,7,11,19,23,27-hexaazatricyclo[27.3.1.113,17]tetratriconta-1(32),2,11,13,15,17(34),18,27,29(33),30-decaene-33,34-diolato-κ10N4,N5,N6,O1,O2:N1,N2,N3,O1,O2]dinickel(II) perchlorate acetonitrile disolvate
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