LIPOXYGENASE-CATALYZED DEHYDRATION OF FURYLHYDROPEROXIDES

被引：2
|
作者：
ANTONIOLETTI, R
BONADIES, F
MONTEAGUDO, ES
ROSSI, A
SCETTRI, A
机构：
[1] UNIV ROME LA SAPIENZA,CNR,CTR STUDIO CHIM SOSTANZE ORGAN NAT,DIPARTIMENTO CHIM,PLE A MORO 5,I-00185 ROME,ITALY
[2] FAC CIENCIAS EXACTAS & NAT BUENOS AIRES,DEPT QUIM ORGAN,BUENOS AIRES,ARGENTINA
来源：
TETRAHEDRON LETTERS | 1992年 / 33卷 / 14期
关键词：
D O I：
10.1016/S0040-4039(00)74178-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
3-alkoxycarbonyl-5(1-hydroperoxyalkyl)-furans 1 are changed into the corresponding 5-acyl and 5-formyl derivatives 2 by a lipoxygenase-catalyzed process. The conversion shows to proceed in enantioselective way leading to chiral furylhydroperoxides and furylalcohols.
引用
收藏
页码：1919 / 1920
页数：2
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