SYNTHESIS OF COMPOUNDS WITH JUVENILE-HORMONE ACTIVITY .30. SYNTHESIS OF (+)-JUVABIONE, A COMPOUND WITH JUVENILE-HORMONE ACTIVITY

被引：15

作者：

NAGANO, E ^{[1
]}

MORI, K ^{[1
]}

机构：

[1] SUMITOMO CHEM CO LTD, TAKARAZUKA RES CTR, TAKARAZUKA, HYOGO 665, JAPAN

来源：

BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY | 1992年 / 56卷 / 10期

关键词：

D O I：

10.1271/bbb.56.1589

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

(+)-Juvabione 1 was synthesized by employing (1R,4S,6S)-6-hydroxybicyclo[2.2.2]octan-2-one 2 as a chiral source. (+)-Juvabione 1 shows juvenile hormone activity, and its racemate has been repeatedly synthesized.1) Optically active 1 was synthesized by Pawson et al. from (+)-limonene,2) and by Trost et al. from (+)-perillaldehyde.3) However, their syntheses were not at all efficient for providing a suitable amount of optically active 1.

引用

页码：1589 / 1591

页数：3

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