SYNTHESIS AND PROPERTIES OF FIRST-GENERATION TO 3RD-GENERATION DENDRIMERS WITH DOUBLY AND TRIPLY BRANCHED CHIRAL BUILDING-BLOCKS

被引：61

作者：

MURER, P ^{[1
]}

SEEBACH, D ^{[1
]}

机构：

[1] ETH ZENTRUM,ORGAN CHEM LAB,CH-8092 ZURICH,SWITZERLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 19期

关键词：

ASYMMETRIC SYNTHESES; CHIRAL DENDRIMERS; CIRCULAR DICHROISM; DENDRIMERS; MASS SPECTROMETRY;

D O I：

10.1002/anie.199521161

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dendrimers with chiral branch components and chiral central units display remarkable CD effects. An interesting case of diastereoselectivity occurs in the synthesis of these compounds: The branch bromide 1 with (S) configuration at the four nonspecific centers can be coupled with the triol 2; the (R) branch bromide 1, on the other hand, cannot! (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2116 / 2119

页数：4

共 43 条

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