SYNTHESIS OF ALLYLSILANES BY PALLADIUM(0) CATALYZED REDUCTION OF TRIALKYLSILYLALLYL ESTERS

被引：0
|
作者：
OLLIVIER, J [1 ]
SALAUN, J [1 ]
机构：
[1] UNIV PARIS 11,INST CHIM MOLEC ORSAY,CARBOCYCLES LAB,CNRS,URA 478,BAT 420,F-91405 ORSAY,FRANCE
来源：
SYNLETT | 1994年 / 11期
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Palladium (0) catalyzed reduction of trialkylsilylallyl esters by hydrides from HCOONa or n-BuZnCl (beta-elimination) led to allylsilanes as major products, offering a new and stereoselective access to these useful electrophilic reagents.
引用
收藏
页码：949 / 951
页数：3
相关论文
共 50 条
  • [1] Palladium(0)-Catalyzed Rearrangement of Allylic Esters
    Jessen, Bo M.
    Ondozabal, Jun Miyatake
    Pedersen, Christian Marcus
    Solvhoj, Amanda
    Taarning, Esben
    Madsen, Robert
    CHEMISTRYSELECT, 2020, 5 (08): : 2559 - 2563
  • [2] REGIOSELECTIVE PALLADIUM(0) CATALYZED REDUCTION OF 1-ALKENYLCYCLOPROPYL ESTERS AS EQUIVALENT OF THE WITTIG REACTION
    OLLIVIER, J
    PIRAS, PP
    STOLLE, A
    AUFRANC, P
    DEMEIJERE, A
    SALAUN, J
    TETRAHEDRON LETTERS, 1992, 33 (23) : 3307 - 3310
  • [3] ASYMMETRIC-SYNTHESIS OF ALLYLSILANES BY PALLADIUM-CATALYZED ASYMMETRIC REDUCTION OF ALLYLIC CARBONATES WITH FORMIC-ACID
    HAYASHI, T
    IWAMURA, H
    UOZUMI, Y
    TETRAHEDRON LETTERS, 1994, 35 (27) : 4813 - 4816
  • [4] PALLADIUM(0)-CATALYZED AZIDATION OF ALLYL ESTERS WITH TRIMETHYLSILYL AZIDE
    SAFI, M
    FAHRANG, R
    SINOU, D
    TETRAHEDRON LETTERS, 1990, 31 (04) : 527 - 530
  • [5] PALLADIUM(0)-CATALYZED HYDROXYLAMINATION OF ALLYL ESTERS - SYNTHESIS OF N-ALLYLHYDROXYLAMINES AND SECONDARY ALLYLAMINES
    MURAHASHI, S
    IMADA, Y
    TANIGUCHI, Y
    KODERA, Y
    TETRAHEDRON LETTERS, 1988, 29 (24) : 2973 - 2976
  • [6] Palladium(0)-catalyzed synthesis of cyclic glucosides
    Huang, Xin
    Fu, Chunling
    Ma, Shengming
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2015, 13 (01) : 248 - 251
  • [7] STRAIN, SILYL AND STERIC EFFECTS ON THE REGIOSELECTIVITY OF PALLADIUM(0) CATALYZED ALLYL ESTERS REDUCTION AS ALTERNATIVE TO THE WITTIG REACTION
    OLLIVIER, J
    DORIZON, P
    PIRAS, PP
    DEMEIJERE, A
    SALAUN, J
    INORGANICA CHIMICA ACTA, 1994, 222 (1-2) : 37 - 49
  • [8] Palladium(0)-Catalyzed Intramolecular Decarboxylative Allylation of Ortho Nitrobenzoic Esters
    Hossian, Asik
    Singha, Shantanu
    Jana, Ranjan
    ORGANIC LETTERS, 2014, 16 (15) : 3934 - 3937
  • [9] Synthesis of Amides and Esters by Palladium(0)-Catalyzed Carbonylative C(sp3)-H Activation
    Carny, Tomas
    Rocaboy, Ronan
    Clemenceau, Antonin
    Baudoin, Olivier
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (43) : 18980 - 18984
  • [10] Fluoride-catalyzed reduction of palladium(II) to palladium(0)-phosphine complexes
    McLaughlin, PA
    Verkade, JG
    ORGANOMETALLICS, 1998, 17 (26) : 5937 - 5940
12345