Synthesis, spectroscopic and electrochemical characterization of nickel(II) and cobalt(II) complexes with new N2S2 ligands, ethyl-and bencyl-N,N'-alkyl-bis(2-amino-1-cyclopentencarbodithioate)

被引：0

作者：

Contreras, Ricardo ^{[1
]}

Aranguren, Jose ^{[1
]}

Bellandi, Fernando ^{[1
]}

Gutierrez, Angel ^{[1
]}

Romero, Isolda ^{[1
]}

Colt, Greis ^{[2
]}

机构：

[1] ULA, Fac Ciencias, Dept Quim, Lab Organomet, Merida, Venezuela

[2] Intevep SA, Lab Corros, Los Teques, Miranda, Venezuela

来源：

CIENCIA E INGENIERIA | 2010年 / 31卷 / 03期

关键词：

Nickel (II) and cobalt (II) complexes; nitrogen-sulfur ligand; beta-dithiolate enamine; inorganic biomimetic;

D O I：

暂无

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The synthesis of nickel(II) and cobalt(II) complexes with the new nitrogen-sulphur ligands, ethyl-N,N'-alkylbis(2-amino-1-cyclopentencarbodithioate) with alkyl = ethylene (L-1), propylene (L-2), butyl (L-3) and benzyl-N,N'-butyl-bis(2-amino-1-cyclopentencarbodithioate) (L-4), and their characterization (UV-Visible, FTIR, H-1- and C-13- NMR, elemental analysis, mass spectra and cyclic voltametry) are reported. The spectroscopic and electrochemical properties of metallic complexes have a potential importance as models in inorganic biomimetic.

引用

页码：153 / 158

页数：6

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