MECHANISM OF PHOTODIMERIZATION REACTION OF 10-METHYLACRIDONE IN POLAR AND NONPOLAR-SOLVENTS

被引：4
|
作者：
KAWATA, H
SHIMADA, K
KUMAGAI, T
NIIZUMA, S
机构：
[1] IWATE UNIV,FAC ENGN,DEPT APPL CHEM,MORIOKA,IWATE 020,JAPAN
[2] TOHOKU UNIV,FAC SCI,DEPT CHEM,SENDAI,MIYAGI 980,JAPAN
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1993年 / 07期
关键词：
D O I：
10.1039/p29930001395
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The photodimerization reaction of 10-methylacridone (1) in the presence of N,N-dimethylaniline (2) was investigated both in deaerated benzene and acetonitrile solutions by a continuous light irradiation (lambda > 350 nm) method and a flash photolysis. The photoreaction proceeds via the triplet state of 1 ((3)1*) and results in electron transfer followed by proton transfer from 2 to 1 to give the dimer, 9,9'-dihydroxy-10,10'-dimethyl-9,9'-biacridan (3).
引用
收藏
页码：1395 / 1398
页数：4
相关论文
共 50 条
  • [1] PHOTODIMERIZATION REACTION OF 10-METHYLACRIDONE
    KAWATA, H
    SHIMADA, K
    KUMAGAI, T
    NIIZUMA, S
    [J]. TETRAHEDRON LETTERS, 1993, 34 (12) : 1935 - 1938
  • [2] PERMITTIVITY OF POLAR SOLUTIONS IN NONPOLAR-SOLVENTS
    OMINI, M
    [J]. IEEE TRANSACTIONS ON ELECTRICAL INSULATION, 1985, 20 (06): : 965 - 973
  • [3] SOLUBILITY OF POLAR GASES IN NONPOLAR-SOLVENTS
    KUZNETSOVA, EM
    RASHIDOVA, DS
    [J]. ZHURNAL FIZICHESKOI KHIMII, 1977, 51 (12): : 3061 - 3063
  • [4] SOLVOLYSIS OF TETRANITROMETHANE IN VARIOUS POLAR AND NONPOLAR-SOLVENTS
    FRANK, AJ
    HENGLEIN, A
    [J]. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1976, 80 (07): : 590 - 593
  • [5] ESTIMATION OF GAS SOLUBILITIES IN POLAR AND NONPOLAR-SOLVENTS
    CYSEWSKI, GR
    PRAUSNITZ, JM
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1976, 15 (04): : 304 - 309
  • [6] SOLUBILITY OF ETHYLENE IN SEVERAL POLAR AND NONPOLAR-SOLVENTS
    SAHGAL, A
    LA, HM
    HAYDUK, W
    [J]. CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1978, 56 (03): : 354 - 357
  • [7] SIMULTANEOUS DETERMINATION OF POLAR AND NONPOLAR-SOLVENTS IN THE WORKPLACE AIR
    GOEN, T
    SOHNLEIN, B
    HUBNER, B
    ANGERER, J
    [J]. STAUB REINHALTUNG DER LUFT, 1994, 54 (03): : 99 - 103
  • [8] FAST PHOTOISOMERIZATION THROUGH A FUNNEL IN POLAR AND NONPOLAR-SOLVENTS
    SMEDARCHINA, ZT
    [J]. DOKLADI NA BOLGARSKATA AKADEMIYA NA NAUKITE, 1985, 38 (09): : 1163 - 1166
  • [9] ENTHALPIES OF INTERACTION OF ALKANES AND ALKENES WITH POLAR AND NONPOLAR-SOLVENTS
    SALUJA, PPS
    YOUNG, TM
    RODEWALD, RF
    FUCHS, FH
    KOHLI, D
    FUCHS, R
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (09) : 2949 - 2953
  • [10] SUPRAMOLECULAR FORMATION OF TRIBLOCK COPOLYMERS IN POLAR NONPOLAR-SOLVENTS
    CHU, B
    WU, GW
    [J]. MACROMOLECULAR SYMPOSIA, 1994, 87 : 55 - 67
12345