The synthesis of UTD-1, Ti-UTD-1 and Ti-UTD-8 using Cp*2CoOH as a structure directing agent

被引：0

作者：

Balkus, KJ ^{[1
]}

Gabrielov, AG ^{[1
]}

Zones, SI ^{[1
]}

机构：

[1] CHEVRON RES & TECHNOL CO,RICHMOND,CA 94802

来源：

ZEOLITES: A REFINED TOOL FOR DESIGNING CATALYTIC SITES | 1995年 / 97卷

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

As part of our effort to advance the application of metal complexes as structure directing agents for molecular sieve synthesis, we discovered that a novel, high silica zeolite (UTD-1) could be prepared using bis(pentamethylcylcopentadienyl) cobalt(III) hydroxide, Cp*2CoOH. UTD-1 has been characterized as a large pore molecular sieve having one dimensional channels running in parallel. The incorporation of titanium into the synthesis gel results in the formation of the titanosilicate, Ti-UTD-1 as well as the novel phase Ti-UTD-8. The preliminary characterization of these materials is described.

引用

页码：519 / 525

页数：7

共 12 条

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