EVIDENCE FOR REMOTE HYPERCONJUGATION THROUGH THE LONG-RANGE DEUTERIUM-ISOTOPE EFFECTS ON C-13 CHEMICAL-SHIFTS

被引：16

作者：

VINKOVIC, V

MLINARICMAJERSKI, K

MARINIC, Z

机构：

[1] Ruder Bošković Institute, 41001 Zagreb

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 48期

关键词：

REMOTE HYPERCONJUGATION; DEUTERIUM ISOTOPE EFFECT; DIASTEREOFACIAL SELECTION;

D O I：

10.1016/S0040-4039(00)60210-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Linear correlation between 4DELTA deuterium isotope effects (DIE) and chemical shifts of carbon atom in position 2 in 2a-j demonstrate evidence for remote hyperconjugation. This is consistent with the Cieplak hyperconjugation model of diastereofacial selection.

引用

页码：7441 / 7444

页数：4

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[1] DEUTERIUM-ISOTOPE EFFECTS ON THE C-13 CHEMICAL-SHIFTS OF CARBOCATIONS
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