PYRIDINE FUNCTIONALIZED ALKYLS OF TRANSITION-METALS - SYNTHESIS OF BIS[C,N-2-PYRIDYLBIS(TRIMETHYLSILYL)METHYL]NICKEL

被引：14

作者：

IZOD, KJ ^{[1
]}

THORNTON, P ^{[1
]}

机构：

[1] QUEEN MARY & WESTFIELD COLL,DEPT CHEM,MILE END RD,LONDON E1 4NS,ENGLAND

来源：

POLYHEDRON | 1993年 / 12卷 / 13期

关键词：

D O I：

10.1016/S0277-5387(00)87071-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Alternate lithiation and reaction with ClSiMe3 of 2.6-dimethylpyridine gave the lithium derivatives of pyridine substituted at the 2- and 6-positions by mono- or bis(trimethylsilyl)methyl groups. The relative ease of formation of these compounds is discussed and compared to their reactivity with transition metal halides. The reaction of NiCl2 with the lithium derivative of bis(trimethylsilyl)methylpyridine gives the remarkably air-stable nickel(II) alkyl bis[C,N-2-pyridylbis(trimethylsilyl)methyl]nickel(II).

引用

页码：1613 / 1620

页数：8

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