GLYCOSYLATION BY 1,2-O-[1-(EXO-CYANO)ETHYLIDENE] DERIVATIVES OF D-MANNURONIC ACID - SYNTHESIS OF MANNOPYRANURONOSYL-MANNOPYRANURONOSIDE DERIVATIVES

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BETANELI, VI
BRUKHANOVA, OV
OTT, AY
MAKAROVA, ZG
KOCHETKOV, NK
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BIOORGANICHESKAYA KHIMIYA | 1992年 / 18卷 / 06期
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Glycosylation of 2-, 3-, and 4-trityl ethers of methyl(methyl-alpha-D-mannopyranoside)uronate by 1,2-O-[1-(exo-cyano)ethylidene]-beta-D-mannopyranuronic acid esters has been investigated, including the effect of high pressure (1.4 GPa) on the stereoselectivity of the reaction. The disaccharides obtained have been deblocked by means of various reaction sequences.
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页码:802 / 817
页数:16
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