The Third Law of Thermodynamics

被引：1

作者：

Rodebush, W. H. ^{[1
]}

机构：

[1] Univ Illinois, Chicago, IL 60680 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1934年 / 2卷 / 10期

关键词：

D O I：

10.1063/1.1749372

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The invariance of statistical weights requires that the entropy of any phase approach zero at 0 degrees K. The uncertainty principle, however, makes it impossible to define a state of absolute zero for a substance whose lowest energy states are closely spaced multiplets.

引用

页数：5

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