A MU-OXO-BIS[IRON(III) PORPHYRIN] COMPLEX

被引：11

作者：

SCHAEFER, WP ^{[1
]}

ELLIS, PE ^{[1
]}

LYONS, JE ^{[1
]}

SHAIKH, SN ^{[1
]}

机构：

[1] SUN CO INC,DEPT RES & DEV,MARCUS HOOK,PA 19061

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270195005701

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Partial nitration of iron(III) 2,3,7,8,12,13,17,18-octaethylporphyrin chloride [Fe-III(OEP)Cl] gives the mu-oxo-bis(5,15-dinitro) compound mu-oxo-bis[2,3,7,8,12,13,17, 18-octaethyl-5,15-dinitroporphyrinato)iron(III)], [Fe-2(C(36)H(4)2N(6)O(4))(2)O], which is similar to other mu-oxo-iron(III) porphyrin complexes but with less ruffling of the porphyrin structure. The porphyrin planes are not parallel [the angle between plane normals is 169 (2)degrees] and the Fe-O-Fe angle is 167.9 (3)degrees. As expected, the Fe atoms are significantly displaced from the porphyrin planes towards the bridging O atom: 0.46 Angstrom for Fe1 and 0.49 Angstrom for Fe2. The two porphyrin residues are eclipsed with respect to their C atoms, but the nitro groups are staggered by 90 degrees from one residue to the other.

引用

页码：2252 / 2255

页数：4

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