A GENERAL-SYNTHESIS OF BETA-HYDROXY ACYLSILANES, ALPHA,BETA-UNSATURATED ACYLSILANES, AND BETA-OXO ACYLSILANES - APPLICATION TO THE SYNTHESIS OF SUGAR DERIVED ACYLSILANES

被引：0
|
作者：
PLANTIERROYON, R [1 ]
PORTELLA, C [1 ]
机构：
[1] UFR SCI,CNRS,REARRANGEMENTS THERM & PHOTOCHIM LAB,BP 347,F-51062 REIMS,FRANCE
来源：
SYNLETT | 1994年 / 07期
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We report a convenient method for synthesis of functionnalized acylsilanes (beta-hydroxy, alpha,beta-unsaturated and beta-oxo-acylsilanes) from epoxides and 2-lithio-2-trimethylsilyl-1,3-dithiane. This method was adapted to 5,6-anhydro-D-glucose derivative to prepare various glucose derived acylsilanes.
引用
收藏
页码：527 / 529
页数：3
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