COMPETITIVE REARRANGEMENTS .1. NEOPENTYLIC VERSUS SKELETAL BICYCLO[2.2.2]OCTANE -] BICYCLO[3.2.1]OCTANE REARRANGEMENTS

被引：0

作者：

IONICA, I

GHIVIRIGA, I

FILIP, P

BADEA, F

DINULESCU, IG

机构：

来源：

REVUE ROUMAINE DE CHIMIE | 1992年 / 37卷 / 09期

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D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Generation of a carbenium ion common to two systems which are able to undergo either a skeletal bicyclo[2.2.2]octane --> bicyclo[3.2.1]octane rearrangement or a neopentylic rearrangement conducts only to the latter reaction. Thus, 8-carbomethoxy-7-t-butyl-dibenzobicyclo[2.2.2]octatriene (15) reacts with strong acids or bromine, yielding neopentyl rearranged products 17, respectively 21. Reaction mechanisms are proposed.

引用

页码：1007 / 1015

页数：9

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