(Di-2-pyridylamine-(KN2)-N-2,N-2')diiodido-palladium(II)

被引：0
|
作者：
Ha, Kwang [1 ]
机构：
[1] Chonnam Natl Univ, Sch Appl Chem Engn, Res Inst Catalysis, Gwangju 500757, South Korea
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
基金：
新加坡国家研究基金会;
关键词：
D O I：
10.1107/S1600536812033946
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The Pdll ion in the title complex, [PdI2(CioH(9)N(3))], is four coordinated in a distorted square-planar environment defined by the two pyridine N atoms of the chelating di-2-pyridylamine (dpa) ligand and two I- anions. The dpa ligand is not planar, the dihedral angle between the pyridine rings being 51.2 (2)degrees. In the crystal, pairs of complex molecules are assembled through intermolecular N-H center dot center dot center dot I hydrogen bonds into dimeric species. The complexes are stacked in columns along the b axis and display several intermolecular pi-pi interactions between the pyridine rings, with a shortest ring centroid-centroid distance of 3.957 (3) angstrom.
引用
收藏
页码：M1144 / +
页数：7
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