AN EASY ROUTE TO CONJUGATED (ALL E) TETRAENE COMPOUNDS VIA DISILYL DERIVATIVES EXEMPLIFIED BY BETA-PARINARIC ACID METHYL-ESTER

被引：0

作者：

BABUDRI, F ^{[1
]}

FIANDANESE, V ^{[1
]}

NASO, F ^{[1
]}

PUNZI, A ^{[1
]}

机构：

[1] UNIV BARI,CNR,CTR STUDIO METODOL INNOVAT SINTESI ORGAN,DIPARTIMENTO CHIM,I-70126 BARI,ITALY

来源：

SYNLETT | 1992年 / 03期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of conjugated (all E) tetraene compounds has been easily achieved in a few steps by electrophilic substitution reactions between (1E,3E)-1,4-bis(trimethylsilyl)-1,3-butadiene (1a) or (1E,3E,5E)-1,6-bis(trimethylsilyl)-1,3,5-hexatriene (1b) and acyl chlorides in the presence of aluminum trichloride, followed by reduction and dehydration reactions. As a representative example, the synthesis of the methyl ester of beta-parinaric acid 6 [methyl (9E,11E,13E,15E)-9,11,13,15-octadecatetraenoate], an interesting fluorophore, is reported.

引用

页码：221 / 223

页数：3