Electrophilic substitution at a saturated carbon by electron deficient nitrogen

被引：88

作者：

Smolinsky, Gerald ^{[1
]}

机构：

[1] Bell Telephone Labs Inc, Murray Hill, NJ USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1960年 / 82卷 / 17期

关键词：

D O I：

10.1021/ja01502a065

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pyrolysis of 2,4,6-trimethyl-2'-azidobiphenyl (I) at 230 degrees resulted in the formation of 2,4,9-trimethylearbazole (IV) and 8,10-dimethylphenanthridine (V). Formation of V results from insertion of the aryl nitrogen into the C-H bond of the o-methyl group of I.

引用

页码：4717 / 4719

页数：3

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