SYNTHESIS OF ENANTIOMERICALLY PURE 5-(L-MENTHYLOXY)-3,4-DIBROMO-2(5H)-FURANONE AND ITS TANDEM ASYMMETRIC MICHAEL ADDITION-ELIMINATION REACTION

被引：0

作者：

CHEN, QH

GENG, Z

HUANG, B

机构：

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel chiral 5-(l-menthyloxy)-3,4-dibromo-2(5H)-furanone 4b was prepared in enantiomerically pure form, and ifs tandem Michael addition-elimination reaction provide the corresponding new chiral sources 6a-6d or 7a-7e, respectively in good yield with de>98%.

引用

页码：401 / 404

页数：4

共 38 条

[1] Synthesis of enantiomerically pure 5-(L-menthyloxy)-3,4-dibromo-2(5H)-furan one and its tandem asymmetric Michael addition-elimination reaction
Chen, Q.
Zhe, G.
Bin, H.
Tetrahedron: Asymmetry, 6 (02):
[2] Optically Pure Synthesis and A Novel Tandem Asymmetric Michael Addition-Elimination Reaction of Chiral 5-(1-Menthyloxy)-3, 4-Dibromo-2-(5H) Furanone
CHEN QingHua
GENG Zhe Department of Chemistry Beijing Normal University Beijing
有机化学, 1993, (03) : 299 - 300
[3] A NOVEL CHIRAL 5-((-)-BORNYLOXY)-3,4-DICHLORO-2(5H)-FURANONE:THE EFFICIENT OPTICALLY PURE SYNTHESIS AND STEREOSPECIFIC TANDEM MICHAEL ADDITION-ELIMINATION REACTION
Qing Hua CHEN Bin HUANC Department of Chemistry
Chinese Chemical Letters, 1993, (08) : 675 - 678
[4] The synthesis and structure of novel chiral intermediate, 5-(l-menthyloxy)-3-bromo-2(5H)-furanone
Huang, H
Chen, QH
ACTA CHIMICA SINICA, 1999, 57 (05) : 538 - 540
[5] Crystal Structure of 5-(l-Menthyloxy)-3-Chloro-4-Pyrolidinyl-2(5H)-Furanone
GENG Zhe (Department of Chemistry
结构化学, 1999, (02) : 35 - 38
[6] Crystal structure of 5-(l-menthyloxy)-3-chloro-4-pyrrolidinyl-2(5H)-furanone
Geng, Z
Chen, QH
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 1999, 18 (02) : 110 - 113
[7] Asymmetric Photocatalyzed Addition of Cyclic Ammes to the Chiral 5-(l)-Menthyloxy-2(5H)-furanone
Zhao Yang WANG
Tian Ying JIAN
Qing Hua CHEN(Department of Chemistry
Chinese Chemical Letters, 1999, (11) : 889 - 892
[8] Asymmetric photocatalyzed addition of cyclic amines to the chiral 5-(l)-menthyloxy-2(5H)-furanone
Wang, ZY
Jian, TY
Chen, QH
CHINESE CHEMICAL LETTERS, 1999, 10 (11) : 889 - 892
[9] Crystal structure of 5-(l-menthyloxy)-3-bromo-4-(R)-(+)-methylbenzylamino-2(5H)-furanone
Geng, Z
Huang, B
Chen, QH
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 1999, 18 (02) : 107 - 109
[10] Crystal Structure of 5-(l-Menthyloxy)-3-Bromo-4-(R)-(+)-Methylbenzylamino-2(5H)-Furanone
GENG Zhe (Department of Chemistry
结构化学, 1999, (02) : 32 - 34

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