THE USE OF SILYL ENOL ETHERS IN THE ALKYLATION OF SUBSTITUTED CYCLANONES

被引：10
|
作者：
ANGERS, P [1 ]
CANONNE, P [1 ]
机构：
[1] UNIV LAVAL, DEPT CHIM, ST FOY G1K 7P4, PQ, CANADA
来源：
TETRAHEDRON LETTERS | 1994年 / 35卷 / 03期
关键词：
ALKYLATION; ALKYL HALIDE; CONJUGATE ADDITION; SILVER TRIFLUOROACETATE; SILYL ENOL ETHER;
D O I：
10.1016/0040-4039(94)85055-0
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reactions of 1-(trimethylsiloxy)-3-methylcyclopent-1-ene, 1-(trimethylsiloxy)-3-methylcyclohex-1-ene and 1-(trimethylsiloxy)-3,3-dimethylcyclohex-1-ene with various alkylating agents in the presence of silver trifluoroacetate produced the corresponding a,3-dialkylated and 2,3,3-trialkylated cyclanones with high regiodifferentiation and stereoselection.
引用
收藏
页码：367 / 370
页数：4
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