Synthesis and W-183 NMR characterization of P4W30Al4(H2O)(2)O-112(20-) heteropolyanion

被引：0

作者：

Meng, L ^{[1
]}

Liu, JF ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 1995年 / 6卷 / 05期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A trivacant heteropolytungstate derivative P4W30Al4(H2O)(2)O-112(20-) has been synthesized from the lacunary precursor Na-12[alpha -P2W15O55]. 24H(2)O and characterized by IR, polarogram and W-188 NMR spectrum, W-188 NMR of the title anion consists of eight lines with intensity ratio 1:2:2:2:2.2:2:2 as expected for the dimeric Dawson-typed anion with C-2h symmetry.

引用

页码：453 / 454

页数：2

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