THE ACTIVE OXYGEN ON THE LI/LA2O3 CATALYST SURFACE AND ITS CATALYTIC BEHAVIOR IN THE OXIDATIVE COUPLING OF METHANE

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作者
WANG, L
WANG, J
YUAN, S
WU, Y
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O64 [物理化学(理论化学)、化学物理学];
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070304 ; 081704 ;
摘要
The coupling selectivity was greatly enhanced by adding Li to La2O3, compared with the single La2O3. The O2- species was found on the Li/La2O3 but not on the single La2O3. In low-temperature desorption, ethane desorbed from the Li/La2O3 but was not detected with the single La2O3. It is considered that the addition of Li gave rise to some basic sites which are favorable for the coupling reaction.
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页码:2205 / 2208
页数:4
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