SELECTIVE CARBONYLATION OF PROPANE IN HF-SBF5 - THE ROLE OF CARBON-MONOXIDE IN THE HALOGEN-PROMOTED ACTIVATION STEP

被引:7
|
作者
BUKALA, J [1 ]
CULMANN, JC [1 ]
SOMMER, J [1 ]
机构
[1] UNIV STRASBOURG 1,FAC CHIM,PHYSICOCHEM HYDROCARBURES LAB,1 RUE BLAISE PASCAL,F-67070 STRASBOURG,FRANCE
关键词
D O I
10.1039/c39920000481
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The halogen-promoted regioselective carbonylation of propane in HF-SbF5 shows a strong dependence of the rates on the partial pressure of CO indicating that carbon monoxide is associated with the halogen in the activation step.
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页码:481 / 483
页数:3
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