Polyquinone synthesis by dehydrogenation agent 3,3 ',5,5 '-tetra-tert-butyl-4,4 '-diphenoquinone

被引：0

作者：

Akhmadullin, Renat M. ^{[1
]}

Gatiyatullin, Dinar R. ^{[2
]}

Akhmadullina, Alfiya G. ^{[1
]}

Verizhnikov, Lev V. ^{[1
]}

Mukmeneva, Natalia A. ^{[2
]}

Gazizov, Almir R. ^{[3
]}

Tagirov, Lenar R. ^{[4
]}

Klochkov, Vladimir V. ^{[5
]}

Yavkin, Boris V. ^{[6
]}

Orlinskii, Sergey B. ^{[6
]}

Nigmatullin, Timur F. ^{[2
]}

机构：

[1] RND Co Ahmadullins Sci & Technol, Kazan, Russia

[2] Kazan Natl Res Technol Univ, Inst Polymers, Dept Synthet Rubber Technol, Kazan, Russia

[3] Russian Acad Sci, Lab Elementoorgan Synth, Kazan Sci Ctr, AE Arbuzov Inst Organ & Phys Chem, Kazan, Russia

[4] KFU, Inst Phys, Dept Solid State Phys, Kazan, Russia

[5] KFU, Inst Phys, Dept Gen Phys, Kazan, Russia

[6] KFU, Inst Phys, Dept Quantum Elect & Radiospect, Kazan, Russia

来源：

RESEARCH JOURNAL OF PHARMACEUTICAL BIOLOGICAL AND CHEMICAL SCIENCES | 2016年 / 7卷 / 02期

关键词：

antioxidants; conjugated polymers; redox polymers; oligomers; high temperature materials;

D O I：

暂无

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

In this article a new approach for polyquinone synthesis is proposed: polymerization of hydroquinone or 1,4-benzoquinone by dehydrogenating agent 3,3',5,5'-tetra-tert-butyl-4,4'-diphenoquinone. Interest to this reaction is emerged from the knowledge of products may have a widespread application, polyquinone due to its pi-conjugated structure with redox-active chains and 4,4'-bis(2,6-di-tert-butylphenol) due to good stabilizing efficiency in polymers. The obtained polyquinone was characterized by spectroscopic, elemental, NMR, EPR and GPC methods and its polymerized nature was proved.

引用

页码：577 / 585

页数：9

共 50 条

[1] DEHYDRATION OF 3,3',5,5'-TETRA-TERT-BUTYL-4,4'-DIPHENOQUINONE - SYNTHESIS OF BIS(THIOPHOSPHORYL)DISULFIDES
LIAKUMOVICH, AG
KADYROVA, VK
MUKMENEVA, NA
BUKHAROV, SV
[J]. ZHURNAL OBSHCHEI KHIMII, 1991, 61 (01): : 260 - 261
[2] OXIDATION OF 2-MERCAPTOBENZOTHIAZOLE BY 3,3',5,5'-TETRA-TERT-BUTYL-4,4'-DIPHENOQUINONE
LIAKUMOVICH, AG
CHEBOTAREVA, EG
ZHARKOVA, VM
KADYROVA, VK
POBEDIMSKII, DG
MUKHMENEVA, NA
[J]. JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1987, 60 (03): : 624 - 626
[3] PARTIAL TRANSALKYLATION OF 3,3', 5,5'-TETRA-TERT-BUTYL-4,4'-DIHYDROXYBIPHENYL
TASHIRO, M
FUKATA, G
[J]. ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 1976, 8 (05) : 241 - 243
[4] New synthetic method for synthesis of 3,3',5,5'-tetra-tert-butyl-4,4'-dihydroxydiphenyl
Ismagilov, RK
Moskva, VV
[J]. ZHURNAL OBSHCHEI KHIMII, 1996, 66 (09): : 1580 - 1580
[5] Structural characterization and electrochemical properties of the 3,3'-5,5-tetra-tert-butyl-4,4′-diphenoquinone
Tumer, Mehmet
Aslantas, Mehmet
Sahin, Ertan
Deligonul, Nihal
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2008, 70 (03) : 477 - 481
[6] Catalytic oxidation of aqueous sulfide in the presence of 3,3′,5,5′-tetra-tert-butyl-4,4′-stilbenequinone
Hoang, H. Y.
Akhmadullin, R. M.
Akhmadullina, F. Yu.
Zakirov, R. K.
Akhmadullina, A. G.
Dao, M. U.
[J]. CHEMICAL ENGINEERING COMMUNICATIONS, 2019, 206 (12) : 1597 - 1607
[7] 3,3′,5,5′-Tetra-tert-butyl-4,4′-diphenoquinone (DPQ)-Air as a New Organic Photocatalytic System: Use in the Oxidative Photocyclization of Stilbenes to Phenacenes
Carrera, Manuel
de la Viuda, Monica
Guijarro, Albert
[J]. SYNLETT, 2016, 27 (20) : 2783 - 2787
[8] STRUCTURES OF 3 RELATED BIPHENYL COMPOUNDS - 4,4'-BIPHENYLDIOL, 3,3',5,5'-TETRA-TERT-BUTYL-4,4'-BIPHENYLDIOL, AND 3,3',5,5'-TETRA-TERT-BUTYL-1,1'-BICYCLOHEXA-2,5-DIENYLIDENE-4,4'-DIONE
JACKISCH, MA
FRONCZEK, FR
GEIGER, CC
HALE, PS
DALY, WH
BUTLER, LG
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 : 919 - 922
[9] Formation of 3,3′,5,5′-tetra(tert-butyl)diphenoquinone and 3,3′,5,5′-tetra(tert-butyl)-4,4′-dihydroxybiphenyl in the reaction of 2-(acetylamino)-3-[3′,5′-di(tert-butyl)-4′-hydroxyphenyl]propanoic acid with thionyl chloride
A. A. Volod’kin
L. N. Kurkovskaya
G. E. Zaikov
S. M. Lomakin
[J]. Russian Chemical Bulletin, 2013, 62 : 2265 - 2265
[10] Formation of 3,3',5,5'-tetra(tert-butyl)diphenoquinone and 3,3',5,5'-tetra(tert-butyl)-4,4'-dihydroxybiphenyl in the reaction of 2-(acetylamino)-3-[3',5'-di(tert-butyl)-4'-hydroxyphenyl]propanoic acid with thionyl chloride
Volod'kin, A. A.
Kurkovskaya, L. N.
Zaikov, G. E.
Lomakin, S. M.
[J]. RUSSIAN CHEMICAL BULLETIN, 2013, 62 (10) : 2265 - 2265

← 1 2 3 4 5 →