X-RAY-DIFFRACTION STUDY OF THE STRUCTURE AND PHASE-TRANSITIONS OF C-60-CLATHRATES

被引:2
|
作者
TEGZE, M [1 ]
BORTEL, G [1 ]
FAIGEL, G [1 ]
OSZLANYI, G [1 ]
PEKKER, S [1 ]
STEPHENS, PW [1 ]
机构
[1] SUNY STONY BROOK,DEPT PHYS,STONY BROOK,NY 11794
基金
匈牙利科学研究基金会;
关键词
D O I
10.1016/0168-583X(94)00734-9
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Phase transition in C-60-dimethoxymethane and C-60-1-bromobutane clathrates were studied by X-ray powder diffraction. Both clathrates show phase transitions corresponding to orientational ordering. Although the two high temperature structures have very similar orthorhombic lattice the phase transitions take place in different ways. In the C-60-dimethoxymethane sample there is no symmetry change while in the C-60-1-bromobutane an orthorhombic to monoclinic transformation of the lattice can be observed.
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页码:585 / 587
页数:3
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