ANGULAR-MOMENTUM IN UNIMOLECULAR REACTIONS

被引：8
|
作者：
KLOTS, CE
机构：
[1] Chemical Physics Section, Oak Ridge National Laboratory, Oak Ridge
来源：
JOURNAL OF CHEMICAL PHYSICS | 1993年 / 98卷 / 01期
关键词：
D O I：
10.1063/1.464656
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Several formulations may be noted for the role of angular momentum in unimolecular reactions. We use here a generalization of the Rice-Gershinowitz model to exemplify their inter-relations. The equations which emerge are simple and equally applicable to loose and tight transition states. Their predictions are compared with experiment and with more tedious calculations.
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页码：206 / 210
页数：5
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