THE CRYSTAL AND MOLECULAR-STRUCTURES OF THE COMPOUNDS [CL4-XSN(CO(CO)4)X] WITH X = 1, 2 AND 3

被引：0

作者：

KLUFERS, P

机构：

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1991年 / 46卷 / 02期

关键词：

TETRACARBONYLCOBALTIO-CHLORO-STANNANES; TIN; COBALT; CARBONYL; X-RAY STRUCTURE;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structures of the compounds [Cl3SnCo(CO)4] 1, [Cl2Sn{Co(CO)4}2] 2, and [ClSn{Co(CO)4}3] 3, have been determined by X-ray crystallography. Sn is co-ordinated tetra-hedrally by Cl- and Co-substituents, the co-ordination polyhedron of Co is a distorted trigonal bipyramid. The Sn-Cl- and the Sn-Co-distances both increase from 1 to 3 (Sn-Co: 247.7 in 1, 253.2 in 2, and 260.6 pm in 3).

引用

页码：187 / 191

页数：5

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