Pyro-synthesis of Na2FeP2O7 Nano-plates as Cathode for Sodium-ion Batteries with Long Cycle Stability

被引:11
|
作者
Song, Jinju [1 ]
Yang, Juhyun [1 ]
Alfaruqi, Muhammad Hilmy [1 ]
Park, Wangeun [1 ]
Park, Sohyun [1 ]
Kim, Sungjin [1 ]
Jo, Jeonggeun [1 ]
Kim, Jaekook [1 ]
机构
[1] Chonnam Natl Univ, Dept Mat Sci & Engn, Gwangju 61186, South Korea
基金
新加坡国家研究基金会;
关键词
Pyro-synthesis; Sodium iron pyrophosphate; Sodium ion batteries;
D O I
10.4191/kcers.2016.53.4.406
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Carbon-coated sodium iron pyrophosphate (Na2FeP2O7) was prepared by a simple and low-cost pyro-synthesis route for further use as the cathode for Na-ion batteries. The X-ray diffraction (XRD) pattern of the sample annealed at 650 degrees C confirmed the pure triclinic phase of Na2FeP2O7. Electron microscopy studies revealed a cross linked plate shape morphology of the Na2FeP2O7 sample. When tested for application in Na-ion battery, the Na2FeP2O7 cathode showed two redox pairs in the potential window of 2.0-4.0 V. The cathode registered initial discharge and charge capacities of 80.85 and 90 mAh/g, respectively, with good cycling performance.
引用
收藏
页码:406 / 410
页数:5
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