ANTI-AROMATICITY AND COLOR IN DYES CONTAINING UNSATURATED 5-MEMBERED RING-SYSTEMS

被引：22
|
作者：
DIETZ, F
TYUTYULKOV, N
RABINOVITZ, M
机构：
[1] HEBREW UNIV JERUSALEM,DEPT ORGAN CHEM,JERUSALEM,ISRAEL
[2] BULGARIAN ACAD SCI,INST ORGAN CHEM,BU-1040 SOFIA,BULGARIA
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1993年 / 02期
关键词：
D O I：
10.1039/p29930000157
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
It is shown that electronic absorption characteristics of many examples of dye molecules containing unsaturated five-membered ring systems can be explained in terms of anti-aromaticity of the rings. The criteria used to assign anti-aromatic character are specified. These are less restrictive than in the original definition of anti-aromaticity given by Breslow.
引用
收藏
页码：157 / 164
页数：8
相关论文
共 50 条
  • [1] AROMATICITY OF 5-MEMBERED RINGS CONTAINING PLATINUM(II)
    HAAKE, P
    CRONIN, PA
    INORGANIC CHEMISTRY, 1963, 2 (04) : 879 - &
  • [2] AROMATICITY AND ANTIAROMATICITY IN 5-MEMBERED C(4)H(4)X RING-SYSTEMS - CLASSICAL AND MAGNETIC CONCEPTS MAY NOT BE ORTHOGONAL
    SCHLEYER, PV
    FREEMAN, PK
    JIAO, HJ
    GOLDFUSS, B
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (03) : 337 - 340
  • [3] VIBRATIONAL-SPECTRA OF MONO AND SPIROCYCLIC 5-MEMBERED RING-SYSTEMS WITH NSISIN UNITS
    BURGER, H
    SCHLINGMANN, M
    PAWELKE, G
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1976, 419 (02): : 121 - 125
  • [4] FLUORESCENT DYES WITH 5-MEMBERED RING CARBOXIMIDE SUBSTRUCTURES
    LANGHALS, H
    GRUNDNER, S
    CHEMISCHE BERICHTE-RECUEIL, 1986, 119 (07): : 2373 - 2376
  • [5] STRUCTURE AND ENERGY-SPECTRA OF MOLECULES CONTAINING ANTIAROMATIC RING-SYSTEMS .3. ANTI-AROMATICITY OF ION RADICALS OF BENZENE AND SUBSTITUTED BENZENES
    DIETZ, F
    RABINOVITZ, M
    TADJER, A
    TYUTYULKOV, N
    ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 1995, 191 : 15 - 22
  • [6] INTRAMOLECULAR CYCLOCONDENSATION OF 4-OXOCARBOXYLIC AND 5-OXOCARBOXYLIC ACIDS TO 5-MEMBERED AND 6-MEMBERED RING-SYSTEMS
    METZ, G
    SCHWENKER, G
    SYNTHESIS-STUTTGART, 1980, (05): : 394 - 397
  • [7] AN ABINITIO STUDY OF INTRAMOLECULAR HYDROGEN-BONDING INTERACTIONS IN 4-MEMBERED, 5-MEMBERED AND 6-MEMBERED RING-SYSTEMS
    GEORGE, P
    BOCK, CW
    TRACHTMAN, M
    JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 1983, 9 (1-2): : 109 - 139
  • [8] DERIVATIVES OF CYCLOOCTATETRAENECYCLOPENTADIENYLTITANIUM CONTAINING SUBSTITUENTS IN 5-MEMBERED RING
    VELDMAN, MEE
    VANOVEN, HO
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 84 (02) : 247 - 253
  • [9] HYDROLYSIS OF A MONOCYCLIC OXYPHOSPHORANE CONTAINING A 5-MEMBERED RING
    MCGALL, GH
    MCCLELLAND, RA
    CANADIAN JOURNAL OF CHEMISTRY, 1991, 69 (12) : 2075 - 2083
  • [10] CYCLIC CONJUGATED 5-MEMBERED AND 7-MEMBERED RING-SYSTEMS .4. NOTE ON SYNTHESIS OF 8-ACETYLHEPTAFULVENE
    HAFNER, K
    ROMER, M
    AUSDERFUNTEN, W
    KOMATSU, K
    TANAKA, S
    OKAMOTO, K
    JUSTUS LIEBIGS ANNALEN DER CHEMIE, 1978, (02): : 376 - 379
12345