EFFECT OF ION-PAIRING ON THE KINETICS OF AQUATION OF BROMOPENTAMMINECOBALT(III) PERCHLORATE IN DICARBOXYLATE-ACETATE MEDIA

被引：0

作者：

ZAGHLOUL, AA

ELSHAZLY, SA

KHALIL, MM

AMIRA, MF

机构：

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1995年 / 34卷 / 01期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Kinetics of aquation of [Co(NH3)5Br]2+ in different types of dicarboxylate solutions containing acetone (10%, v/v), at different temperatures have been investigated in the light of the effects of ion-pairing on reaction rates and mechanism. A new empirical correlation between the rate coefficient and the stoichiometric concentration of the ion-pairing dicarboxylate ligand (C1) has been established and a reaction mechanism is proposed.

引用

页码：52 / 54

页数：3

共 48 条

[1] EFFECT OF ION-PAIRING ON THE KINETICS OF AQUATION OF BROMOPENTAMINECOBALT(III) PERCHLORATE IN DICARBOXYLATE-ACETONE MEDIA (VOL 34, PG 52, 1995)
ZAGHLOUL, AA
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1995, 34 (03): : 248 - 248
[2] Kinetics of aquation of bromopentamminecobalt(III) perchlorate in mixed aqueous solvents
Zaghloul, AA
ElShazly, SA
Odah, KA
Amira, MF
AbdelHalim, FM
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1996, 73 (11) : 572 - 575
[3] KINETICS OF AQUATION OF BROMOPENTAMMINECOBALT(III) PERCHLORATE IN DICARBOXYLATE MEDIA CONTAINING 20-PERCENT (V/V) ETHYLENE-GLYCOL
ZAGHLOUL, AA
MOHAMED, MT
ELSHAZLY, SHA
HALIM, FMA
AMIRA, MF
AFINIDAD, 1992, 49 (442) : 383 - 389
[4] EMF AND KINETIC-STUDIES OF THE ION-PAIRING EFFECTS ON THE RATE OF AQUATION OF CHLOROPENTAMMINECHROMIUM(III) PERCHLORATE IN DIFFERENT DICARBOXYLATE MEDIUM
AMIRA, MF
ELSHAZLY, SA
KHALIL, MM
ABDELHALIM, FM
TRANSITION METAL CHEMISTRY, 1986, 11 (02) : 72 - 74
[5] EFFECT OF ION-PAIRING ON SOLVOLYTIC AQUATION OF BROMOPENTAAMMINECOBALT(III) ION IN PRESENCE OF SULFATE ANION
PANDA, A
NAIK, NC
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1986, 25 (09): : 858 - 860
[6] EFFECT OF ION-PAIRING ON SOLVOLYTIC AQUATION OF BROMOPENTAAMMINECOBALT(III) ION IN PRESENCE OF OXALATE ANION
PANDA, A
NAIK, NC
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1988, 27 (05): : 439 - 441
[7] Aquation kinetics of chloropentamminecobalt (III) perchlorate in dicarboxylate media containing 10% (v/v) acetone
Alexandria Univ, Alexandria, Egypt
Int J Chem Kinet, 4 (311-316):
[8] Aquation kinetics of chloropentamminecobalt(III) perchlorate in dicarboxylate media containing 10% (v/v) acetone
Zaghloul, AA
Khalil, MM
Amira, MF
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1997, 29 (04) : 311 - 316
[9] EFFECT OF ION-PAIRING ON SOLVOLYTIC AQUATION OF CHLOROPENTAAMMINECOBALT(III) ION IN PRESENCE OF MALONATE AND SUCCINATE ANIONS
NAIK, NC
NANDA, RK
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1976, 53 (02) : 149 - 152
[10] KINETICS AND MECHANISM FOR THE AQUATION OF BISMALONATOETHYLENEDIAMINECOBALTATE(III) ION IN ACID PERCHLORATE-MEDIA
DAS, S
BHATTACHARYA, S
BANERJEE, RN
BANERJEA, D
TRANSITION METAL CHEMISTRY, 1982, 7 (05) : 249 - 252

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