CONVENIENT SYNTHESIS OF DIENE ZIRCONOCENES AND REGIOSELECTIVE PARTIAL REDUCTION OF THE MORE HIGHLY SUBSTITUTED DOUBLE-BONDS OF CONJUGATED DIENES VIA COMPLEXATION WITH ZIRCONOCENES AND PROTONOLYSIS

被引：7

作者：

MAYE, JP ^{[1
]}

NEGISHI, E ^{[1
]}

机构：

[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 24期

关键词：

D O I：

10.1039/c39930001830

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Conjugated dienes can be initially converted to their zirconocene complexes most conveniently by their reaction with (C5H5)2ZrCl2 and freshly ground Mg; the resultant complexes can then be protonolysed with 3 mol dm-3 HCl to give regioselectively monoenes corresponding to partial hydrogenation of the more highly substituted double bond.

引用

页码：1830 / 1831

页数：2