VIBRATIONAL ANALYSIS OF NAM(2)OH(H2O)(MOO4)(2)/D-2/O [M=NI, ZN]

被引：5

作者：

RATHEESH, R ^{[1
]}

SURESH, G ^{[1
]}

NAYAR, VU ^{[1
]}

机构：

[1] UNIV KERALA,DEPT PHYS,TRIVANDRUM 695581,KERALA,INDIA

来源：

PRAMANA-JOURNAL OF PHYSICS | 1995年 / 44卷 / 05期

关键词：

INFRARED SPECTRUM; RAMAN SPECTRUM; HYDROGEN BONDING;

D O I：

10.1007/BF02848498

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

The infrared and Raman spectra of NaNi2OH(H2O)(MoO4)(2) and NaZn2OH (H2O)(MoO4)(2) and their partially deuterated analogues are recorded and analysed on the basis of vibrations of MoO42- tetrahedra and H2O molecules. The MoO42- groups are found to be more distorted in NaNi2 OH(H2O)(MoO4)(2) than in the other compound. Bands indicating the presence of H2O+ ions are not observed in NaZn2 OH(H2O)(MoO4)(2) ruling out the possibility of the formulation of NaZn2OHO(MoO3OH)(2). Hydrogen bonds of medium strength are present in both the compounds.

引用

页码：461 / 470

页数：10

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