USING KNOWN MECHANISMS TO SYNTHESIZE NEW COMPOUNDS - PREPARATION AND CHARACTERIZATION OF TRANS-[CO(NH3)4(NH2CH3)L]2+ (L=NO2- OR ONO-) COMPLEXES

被引：0

作者：

MASSAFERRO, A

QUEIROLO, M

SIENRA, B

机构：

来源：

ANALES DE QUIMICA-INTERNATIONAL EDITION | 1992年 / 88卷 / 02期

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D O I：

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中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The syntheses of the linkage isomers trans-[Co (NH3)4 (NH2CH3)NO2]2+ and trans -[Co(NH3)4 (NH2CH3)ONO]2+ are reported. The methods of preparation of these complexes are based on the mechanism proposed earlier for the formation of the known parent pentaammines. The complexes are characterized by means of electronic, infrared and proton magnetic resonance spectroscopy. The trans configurations of the new complexes are established on the basis of their H-1 NMR spectra.

引用

页码：230 / 233

页数：4

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[1] SYNTHESIS, CHARACTERIZATION AND SOME REACTIONS OF TRANS-[CO(NH3)4(CH3NH2)BR]2+ AND TRANS-[CO(NH3)4(CH3NH2)(NO3)]2+ COMPLEXES
SIENRA, B
MASSAFERRO, A
MACCOLL, CRP
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1990, 590 (11): : 222 - 228
[2] SYNTHESIS AND CHARACTERIZATION OF TRANS-[CO(NH3)4(NH2CH3)L]3+ [L = (CH3)2SO OR (CH3)2NCHO] COMPLEXES
SIENRA, B
MASSAFERRO, A
POLYHEDRON, 1991, 10 (17) : 2075 - 2078
[3] Spontaneous and base-catalyzed nitrito to nitro linkage isomerization of trans-[Co(NH3)4(NH2CH3)ONO]2+ complex
Bozoglian, F
Queirolo, M
Sienra, B
POLYHEDRON, 1998, 17 (20) : 3551 - 3556
[4] Molecular structure of trans-[Co(NH3)4(NH2CH3)Cl](ClO4)2
Fabián Benzo
Beatríz Sienra
Oscar E. Piro
Journal of Chemical Crystallography, 1998, 28 : 69 - 72
[5] Molecular structure of trans-[Co(NH3)4(NH2CH3)Cl](ClO4)2
Benzo, F
Sienra, B
Piro, OE
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1998, 28 (01) : 69 - 72
[6] Competition study for the base hydrolysis of trans-[Co(NH3)4(NH2CH3)X]n+ complexes
Benzo, F
Mendoza, C
Queirolo, H
Sienra, B
POLYHEDRON, 1998, 17 (13-14) : 2295 - 2299
[7] Electronic spectra of trans-[Ru(NH3)4(L)NO]3+/2+ complexes
Gorelsky, SI
da Silva, SC
Lever, ABP
Franco, DW
INORGANICA CHIMICA ACTA, 2000, 300 : 698 - 708
[8] STRUCTURAL CHARACTERIZATION OF TRANS-[CR(NH3)4(H2O)CL]CL2 AND TRANS-[CR(NH3)4CL2]L
BRENCIC, JV
LEBAN, I
ZULE, J
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1985, 521 (02): : 199 - 206
[9] ISONICOTINAMIDE AS ENTERING LIGAND ON TRANS-[RU(NH3)4P(OME)3(H2O)]2+, TRANS-[RU(NH3)4P(OPR)3(H2O)]2+, TRANS-[RU(NH3)4P(OIPR)3(H2O)]2+, TRANS-[RU(NH3)4P (OBU)3(H2O)]2+
DONASCIMENTO, JC
FRANCO, DW
INORGANICA CHIMICA ACTA, 1986, 113 (01) : 55 - 60
[10] NMR spectroscopic characterization of methylcobalt(III) compounds with classical ligands. Crystal structures of [Co(NH3)(5)(CH3)]S2O6, trans-[Co(en)(2)(NH3)(CH3)]S2O6 (en equals 1,2-ethanediamine), and [Co(NH3)(6)]-mer,trans-[Co(NO2)(3)(NH3)(2)(CH3)](2)-trans-[Co(NO2)(4)(NH3)(2)]
Kofod, P
Harris, P
Larsen, S
INORGANIC CHEMISTRY, 1997, 36 (11) : 2258 - 2266

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