SYNTHESIS, STRUCTURE, ELECTRIC, AND MAGNETIC-PROPERTIES OF CANIN

被引：90
|
作者：
CHERN, MY
DISALVO, FJ
机构：
[1] Department of Chemistry, Cornell University, Ithaca
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 1990年 / 88卷 / 02期
关键词：
D O I：
10.1016/0022-4596(90)90242-P
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
We report the synthesis and physical properties of the new ternary nitride CaNiN, prepared by the reaction of Ca3N2 and Ni in N2 gas at 1000°C. The structure, determined by the method of X-ray powder diffraction, is tetragonal ( P42 mmc) with a = 3.5809(2) Å, c = 7.0096(3) Å, and Z = 2. While the structure is a simple but uncommone one, with all atoms occupying fixed special positions, it features interesting-NiNNiN-linear chains. Conductivity and magnetic measurements show that CaNiN is metallic and paramagnetic. © 1990.
引用
收藏
页码：459 / 464
页数：6
相关论文
共 50 条
  • [1] SYNTHESIS, STRUCTURE, AND MAGNETIC-PROPERTIES OF NONACHLORODIMOLYBDATES(III)
    SPITSIN, VI
    KAZIN, PE
    SUBBOTIN, MI
    ASLANOV, LA
    ZELENTSOV, VV
    SHIROV, AI
    FELIN, MG
    DOKLADY AKADEMII NAUK SSSR, 1986, 287 (01): : 134 - 139
  • [2] ORGANIC SUPERCONDUCTORS - SYNTHESIS, STRUCTURE, CONDUCTIVITY, AND MAGNETIC-PROPERTIES
    WILLIAMS, JM
    CARNEIRO, K
    ADVANCES IN INORGANIC CHEMISTRY, 1985, 29 : 249 - 296
  • [3] HYDROTHERMAL SYNTHESIS, STRUCTURE AND MAGNETIC-PROPERTIES OF BARIUM DIFERRITE
    OKAMOTO, S
    SEKIZAWA, H
    OKAMOTO, SI
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1975, 36 (06) : 591 - 595
  • [4] ELECTRIC AND MAGNETIC-PROPERTIES OF THE BRCL MOLECULE
    FOWLER, PW
    LEGON, AC
    PEEBLES, SA
    STEINER, E
    CHEMICAL PHYSICS LETTERS, 1995, 238 (1-3) : 163 - 167
  • [5] ELECTRIC AND MAGNETIC-PROPERTIES OF HOT GLUONS
    HANSSON, TH
    ZAHED, I
    PHYSICAL REVIEW LETTERS, 1987, 58 (23) : 2397 - 2399
  • [6] STRUCTURE AND MAGNETIC-PROPERTIES OF TBMNGA
    BACMANN, M
    FRUCHART, D
    SOUBEYROUX, JL
    BRABERS, JHVJ
    DEBOER, FR
    BUSCHOW, KHJ
    JOURNAL OF ALLOYS AND COMPOUNDS, 1994, 209 : 135 - 138
  • [7] MAGNETIC-PROPERTIES AND STRUCTURE OF OXYHEMOGLOBIN
    PAULING, L
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1977, 74 (07) : 2612 - 2613
  • [8] EFFECT OF ANTIMONY ON MAGNETIC-PROPERTIES AND STRUCTURE OF NON-ORIENTATED ELECTRIC SHEETS
    SOLYOM, A
    FRIC, V
    MARKO, P
    KOVOVE MATERIALY-METALLIC MATERIALS, 1995, 33 (01): : 15 - 21
  • [9] ELECTRIC AND MAGNETIC-PROPERTIES OF COMPLEXES OF TCNQ ANION RADICAL SALTS .2. MAGNETIC-PROPERTIES
    CIESIELSKI, W
    KRYSZEWSKI, M
    ROCZNIKI CHEMII, 1976, 50 (06): : 1159 - 1167
  • [10] ELECTRIC AND MAGNETIC-PROPERTIES OF ORGANOMETALLIC TCNQ SALTS
    PUKACKI, W
    GRAJA, A
    SYNTHETIC METALS, 1988, 24 (1-2) : 137 - 143
12345