CYCLOPALLADATED COMPLEXES - SYNTHESIS AND CRYSTAL-STRUCTURE OF DI-MU-CHLORO-BIS([2,6-DIMETHYL-N-(BENZYLIDENE)PHENYLAMINATO-C2',N]PALLADIUM(II))

被引：38

作者：

CRISPINI, A ^{[1
]}

DEMUNNO, G ^{[1
]}

GHEDINI, M ^{[1
]}

NEVE, F ^{[1
]}

机构：

[1] UNIV CALABRIA,DIPARTIMENTO CHIM,I-87030 ARCAVACATA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 427卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)80078-C

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The X-ray crystal structure of the cyclometallated palladium(II) complex [{Pd(L2)(mu-Cl)}2], L2 = 2,6-dimethyl-N-(benzylidene)phenylaminate, is described. Crystals were orthorhombic, space group Pna2(1) with a = 17.307(3) angstrom, b = 17.732(4) angstrom, c = 9.075 angstrom, Z = 4, U = 2785.0(10) angstrom3. The palladated dimer, with asymmetrically bridging chlorine atoms, exhibits a Pd2Cl2 unit folded at 36.7(1)-degrees and a non-bonding Pd ... Pd separation of 3.425(1) angstrom.

引用

页码：409 / 414

页数：6

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