ACCURATE DETERMINATION OF THE FIRST IONIZATION-POTENTIAL OF ACTINIDES BY LASER SPECTROSCOPY

被引：9
|
作者：
TRAUTMANN, N
机构：
[1] Institut für Kemchemie, Universität Mainz
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 1994年 / 213卷
关键词：
D O I：
10.1016/0925-8388(94)90876-1
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new method is described for the precise determination of the first ionization potential of elements which are available only in small amounts such as the heavier actinides. It is based on resonance ionization mass spectroscopy (RIMS) in the presence of an external electric field. Extrapolation of the ionization thresholds obtained with different electric field strengths to field strength zero leads directly to the first ionization potential. With samples of 10(12) atoms of Np-237 and Am-243 experimental values for the first ionization potential of neptunium of IPNp = 6.2655(2) eV and of americium of IPAm = 5.9738(2) eV were obtained. This technique was also applied to thorium yielding a value of IPTh = 6.3067(2) eV. In addition the precision of the method was confirmed by the convergences of Rydberg series of americium measured by means of RIMS.
引用
收藏
页码：28 / 32
页数：5
相关论文
共 50 条
  • [1] FIRST DETERMINATION OF THE IONIZATION-POTENTIAL OF AMERICIUM AND CURIUM
    DEISSENBERGER, R
    KOHLER, S
    AMES, F
    EBERHARDT, K
    ERDMANN, N
    FUNK, H
    HERRMANN, G
    KLUGE, HJ
    NUNNEMANN, M
    PASSLER, G
    RIEGEL, J
    SCHEERER, F
    TRAUTMANN, N
    URBAN, FJ
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (07): : 814 - 815
  • [2] IONIZATION-POTENTIAL OF NEUTRAL ATOMIC PLUTONIUM DETERMINED BY LASER SPECTROSCOPY
    WORDEN, EF
    CARLSON, LR
    JOHNSON, SA
    PAISNER, JA
    SOLARZ, RW
    JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1993, 10 (11) : 1998 - 2005
  • [3] DIRECT DETERMINATION OF THE IONIZATION-POTENTIAL OF CO BY RESONANTLY ENHANCED MULTIPHOTON IONIZATION MASS-SPECTROSCOPY
    ERMAN, P
    KARAWAJCZYK, A
    RACHLEWKALLNE, E
    STROMHOLM, C
    LARSSON, J
    PERSSON, A
    ZERNE, R
    CHEMICAL PHYSICS LETTERS, 1993, 215 (1-3) : 173 - 178
  • [4] THE IONIZATION-POTENTIAL OF NEUTRAL IRON, FE-I, BY MULTISTEP LASER SPECTROSCOPY
    WORDEN, EF
    COMASKEY, B
    DENSBERGER, J
    CHRISTENSEN, J
    MCAFEE, JM
    PAISNER, JA
    CONWAY, JG
    JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1984, 1 (02) : 314 - 316
  • [5] Measurement of the first ionization potential of astatine by laser ionization spectroscopy
    Rothe, S.
    Andreyev, A. N.
    Antalic, S.
    Borschevsky, A.
    Capponi, L.
    Cocolios, T. E.
    De Witte, H.
    Eliav, E.
    Fedorov, D. V.
    Fedosseev, V. N.
    Fink, D. A.
    Fritzsche, S.
    Ghys, L.
    Huyse, M.
    Imai, N.
    Kaldor, U.
    Kudryavtsev, Yuri
    Koester, U.
    Lane, J. F. W.
    Lassen, J.
    Liberati, V.
    Lynch, K. M.
    Marsh, B. A.
    Nishio, K.
    Pauwels, D.
    Pershina, V.
    Popescu, L.
    Procter, T. J.
    Radulov, D.
    Raeder, S.
    Rajabali, M. M.
    Rapisarda, E.
    Rossel, R. E.
    Sandhu, K.
    Seliverstov, M. D.
    Sjoedin, A. M.
    Van den Bergh, P.
    Van Duppen, P.
    Venhart, M.
    Wakabayashi, Y.
    Wendt, K. D. A.
    NATURE COMMUNICATIONS, 2013, 4
  • [6] Measurement of the first ionization potential of astatine by laser ionization spectroscopy
    S. Rothe
    A. N. Andreyev
    S. Antalic
    A. Borschevsky
    L. Capponi
    T. E. Cocolios
    H. De Witte
    E. Eliav
    D. V. Fedorov
    V. N. Fedosseev
    D. A. Fink
    S. Fritzsche
    L. Ghys
    M. Huyse
    N. Imai
    U. Kaldor
    Yuri Kudryavtsev
    U. Köster
    J. F. W. Lane
    J. Lassen
    V. Liberati
    K. M. Lynch
    B. A. Marsh
    K. Nishio
    D. Pauwels
    V. Pershina
    L. Popescu
    T. J. Procter
    D. Radulov
    S. Raeder
    M. M. Rajabali
    E. Rapisarda
    R. E. Rossel
    K. Sandhu
    M. D. Seliverstov
    A. M. Sjödin
    P. Van den Bergh
    P. Van Duppen
    M. Venhart
    Y. Wakabayashi
    K. D. A. Wendt
    Nature Communications, 4
  • [7] RIMS measurements for the determination of the first ionization potential of the actinides actinium up to einsteinium
    Waldek, A
    Erdmann, N
    Grüning, C
    Huber, G
    Kunz, P
    Kratz, JV
    Lassen, J
    Passler, G
    RESONANCE IONIZATION SPECTROSCOPY 2000, 2001, 584 : 219 - 224
  • [8] FIRST IONIZATION-POTENTIAL OF PLATINUM BY MASS-SELECTED DOUBLE-RESONANCE FIELD-IONIZATION SPECTROSCOPY
    MARIJNISSEN, A
    TERMEULEN, JJ
    HACKETT, PA
    SIMARD, B
    PHYSICAL REVIEW A, 1995, 52 (04): : 2606 - 2610
  • [9] ACCURATE DETERMINATION OF 1ST IONIZATION-POTENTIAL OF CLO(X2PII) RADICAL USING PHOTOELECTRON-SPECTROSCOPY
    BULGIN, DK
    DYKE, JM
    JONATHAN, N
    MORRIS, A
    MOLECULAR PHYSICS, 1976, 32 (05) : 1487 - 1489
  • [10] IONIZATION-POTENTIAL OF THORIUM
    HILDENBRAND, DL
    MURAD, E
    JOURNAL OF CHEMICAL PHYSICS, 1974, 61 (12): : 5466 - 5467
12345